Der Artikel ist weiterhin als ^^OTHERCONDITION^^ verfügbar.
Autor: R. Pecora
ISBN-13: 9780306417900
Einband: Buch
Seiten: 420
Gewicht: 786 g
Format: 22.9x15.2x cm
Sprache: Englisch

Dynamic Light Scattering

Applications of Photon Correlation Spectroscopy
1 Introduction.- References.- 2 Light Scattering Apparatus.- 2.1. Introduction.- 2.2. Electromagnetic Waves.- 2.3. Light Scattering.- 2.3.1. Background.- 2.3.2. Fluctuations.- 2.3.3. The Coherence Area.- 2.3.4. Time Dependence.- 2.3.5. Local Oscillator.- 2.4. The Light Scattering Experiment.- 2.4.1. Introduction.- 2.4.2. The Light Source.- 2.4.3. The Spectrometer.- 2.4.4. The Detector.- 2.4.5. Signal Analyzers.- 2.5. Signal-to-Noise Ratio.- 2.5.1. Introduction.- 2.5.2. Effects due to Finite Intensity.- 2.5.3. Effects due to Finite Experiment Duration.- 2.5.4. Effects due to Unwanted Scattered Light.- 2.6. Data Analysis.- 2.6.1. Introduction.- 2.6.2. Selecting the Theoretical Form.- 2.6.3. Use of the ?2Test.- 2.6.4. Summary of Possible Forms.- 2.6.5. Polydispersity.- 2.7. Special Apparatus.- 2.7.1. Electrophoretic Light Scattering.- 2.7.2. Fabry-Perot Interferometers.- 2.7.3. Software Correlators.- 2.7.4. Cross-Correlation Experiment.- 2.8. Conclusions.- References and Notes.- 3 Dynamic Depolarized Light Scattering.- 3.1. Introduction.- 3.2. Principles of Depolarized Scattering.- 3.2.1. Scattering Configurations.- 3.2.2. Physical Principles.- 3.3 Rigid Macromolecules in Dilute Solution.- 3.3.1. Hydrodynamics of Rigid Macromolecules.- 3.3.2. Interferometric Studies.- 3.3.3. Photon Correlation Studies.- 3.4. Rod-Shaped Macromolecules in Semidilute Solutions.- 3.5. Flexible Macromolecules.- 3.6. Rotation of Small Molecules in Viscous Media.- 3.7. Resonance-Enhanced Depolarized Dynamic Light.- Scattering.- References and Notes.- 4 Particle Interactions.- 4.1. Introduction.- 4.2. Quantities Measured by Light Scattering.- 4.2.1. Introduction.- 4.2.2. Monodisperse Systems.- 4.2.3. Polydisperse Systems.- 4.2.4. Discussion.- 4.3.Theory.- 4.3.1. Introduction.- 4.3.2. Stokes-Einstein Relations.- 4.3.3. The Generalized Smoluchowski Equation.- 4.3.4. Hydrodynamic Interactions.- 4.3.5. Short-Time Motions.- 4.3.6. Projection Operator Analysis.- 4.3.7. Dynamics in the Small-q Limit-Cooperative and Self-Diffusion.- 4.4. Charged Particles in Dilute Suspension (Negligible Hydrodynamic Interactions).- 4.4.1. Introduction.- 4.4.2. Single-Particle Motions.- 4.4.3. The First Cumulant.- 4.4.4. Low-g Limit and the Effect of Polydispersity.- 4.4.5. Memory Effects.- 4.5. Effects of Hydrodynamic Interactions.- 4.5.1. Introduction.- 4.5.2. Theory of the Collective Diffusion Coefficient in the Hydrodynamic Regime.- 4.5.3. Experimental Results.- 4.5.4. Microemulsions.- 4.5.5. Hydrodynamic Effects at Finite q.- 4.6. Small-Ion Effects.- 4.7. Conclusions.- 4.8. Addendum.- References and Notes.- 5 Quasielastic Light Scattering from Dilute and Semidilute Polymer Solution.- 5.1. Introduction.- 5.2.The Single Chain.- 5.2.1. Basic Polymer Statistics.- 5.2.2. Dynamical Regimes.- 5.2.3. Center-of-Mass Diffusion (q R 1).- 5.2.4. Internal Dynamics and the Dynamic Structure Factor.- 5.3. Virial Regime.- 5.4. Semidilute Solutions.- 5.4.1. Introduction.- 5.4.2. Dynamical Regimes.- 5.4.3. Conclusions.- References.- 6Dynamic Light Scattering in Bulk Polymers.- 6.1. Introduction.- 6.2. Light Scattering.- 6.3. Sources of Light Scattering.- 6.4. Theory.- 6.5. Applications.- 6.5.1. Brillouin Spectroscopy.- 6.5.2. Dynamic Central Peaks.- 6.5.3. Depolarized Rayleigh Scattering.- 6.6. Conclusions.- References.- 7 Critical Phenomena.- 7.1. Introduction.- 7.2. Critical Fluctuations.- 7.2.1. Static Critical Behavior.- 7.2.2. Dynamic Critical Behavior.- 7.3. Depolarized Rayleigh Scattering.- 7.4 .Entropy Fluctuations.- 7.4.1. Entropy Rayleigh Factor.- 7.4.2. Local Entropy Fluctuations.- 7.5. Multicomponent Fluids.- 7.5.1. Ternary Liquid Mixtures.- 7.5.2. Binary Fluid in the Presence of Isotope Exchange....- 7.5.3. Tricritical Point Behavior.- 7.6. Spinodal Decomposition and Critical Behavior Induced by Shear Flow.- 7.6.1. Spinodal Decomposition.- 7.6.2. Critical Behavior Induced by Shear Flow.- References.- 8 Laser Light Scattering in Micellar Systems.- 8.1. Introduction.- 8.2. The
In the twenty years since their inception, modern dynamic light-scattering techniques have become increasingly sophisticated, and their applications have grown exceedingly diverse. Applications of the techniques to problems in physics, chemistry, biology, medicine, and fluid mechanics have prolifer ated. It is probably no longer possible for one or two authors to write a monograph to cover in depth the advances in scattering techniques and the main areas in which they have made a major impact. This volume, which we expect to be the first of aseries, presents reviews of selected specialized areas by renowned experts. It makes no attempt to be comprehensive; it emphasizes a body of related applications to polymeric, biological, and colloidal systems, and to critical phenomena. The well-known monographs on dynamic light scattering by Berne and Pecora and by Chu were published almost ten years ago. They provided comprehensive treatments of the general principles of dynamic light scat tering and gave introductions to a wide variety of applications, but natu rally they could not treat the new applications and advances in older ones that have arisen in the last decade. The new applications include studies of interacting particles in solution (Chapter 4); scaling approaches to the dynamics of polymers, including polymers in semidilute solution (Chapter 5); the use of both Fabry-Perot interferometry and photon correlation spectroscopy to study bulk polymers (Chapter 6); studies of micelIes and microemulsions (Chapter 8); studies of polymer gels (Chapter 9).
Autor: R. Pecora
ISBN-13:: 9780306417900
ISBN: 0306417901
Verlag: Springer, Berlin
Gewicht: 786g
Seiten: 420
Sprache: Englisch
Sonstiges: Buch, 22.9x15.2x cm, 2 SW-Abb.